By J.C. Jones

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Preliminaries. 4 u 108 kg year-1 (| a quarter of a million tonne per year) 2. Stoichiometric calculations. A diesel with cetane number 50 would correspond in performance terms to a blend of 50% n-cetane C16H34 and 50% alpha-methyl naphthalene C11H10. It is elementary to show that such a mixture would have elemental composition 85% carbon 15% hydrogen. 189 kg. 4 N2) If (as would be usual) combustion was in excess air to the extent of say 20%, per kg of the hydrocarbon burnt the post-combustion gases would be: CO2 74 mole, H2O (vapour) 56 mole, N2 460 mole, O2 20 mole.

5 million. com 63 Atmospheric Pollution Metals in the atmosphere 7. ) molar basis if the lead is present in elemental form. A similar figure has been set by the EPA in the US. There has been a dramatic reduction in lead release over the last thirty years since unleaded petrol came into widespread use (see next section). Even so, the annual release of lead into the atmosphere in the US is 1300 tons. It is believed that releases of this order are sufficient to be harmful, especially to children. A calculation similar to those done previously for VOC and for carbon monoxide follows.

4 u 108 kg year-1 (| a quarter of a million tonne per year) 2. Stoichiometric calculations. A diesel with cetane number 50 would correspond in performance terms to a blend of 50% n-cetane C16H34 and 50% alpha-methyl naphthalene C11H10. It is elementary to show that such a mixture would have elemental composition 85% carbon 15% hydrogen. 189 kg. 4 N2) If (as would be usual) combustion was in excess air to the extent of say 20%, per kg of the hydrocarbon burnt the post-combustion gases would be: CO2 74 mole, H2O (vapour) 56 mole, N2 460 mole, O2 20 mole.

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